Buchler Glossary

(Asymmetric) Oxohydroxylation

Asymmetric oxohydroxylation of α-alkyl enoates with potassium permanganate catalyzed by monocationic quaternary ammonium salts derived from Cinchona alkaloid is performed with an alkene furnishing adjacent oxo and hydroxy groups,

Further Articles:

Alkylation

Alkylation is the introduction of an alkyl group into an organic compound by substitution or addition. The alkyl group...

Alkynylation

Alkynylation is an addition reaction in organic synthesis where a terminal alkyne adds to a carbonyl group to form an...

Allylsilylation

An Allylsilylation is performed between allylsilanes and aldehydes furnishes homo allyl alcohols. Using Cinchona...

Amination

Amination is the process by which an amine group is introduced into an organic molecule. This type of reaction is...

Aminohydroxylation

The Sharpless Aminohydroxylation allows the syn-selective preparation of 1,2-amino alcohols by reaction of alkenes...

Aromatic System

Any hydrocarbon or heterocycle with 4n+2 electrons in a fully conjugated cyclic π system is considered to be an...