Asymmetric Dihydroxylation of olefins is of high synthetic value because it introduces two vicinal hydroxy groups,...
Buchler Glossary
Aminohydroxylation
The Sharpless Aminohydroxylation allows the syn-selective preparation of 1,2-amino alcohols by reaction of alkenes with salts of N-halosulfonamides, -amides and -carbamates using OsO4 as a catalyst. Enantioselectivity is achieved through the addition of Dihydroquinine– and Dihydroquinidine-derived chiral ligands.
Further Articles:
(Asymmetric) Oxohydroxylation
Asymmetric oxohydroxylation of α-alkyl enoates with potassium permanganate catalyzed by monocationic quaternary...
(Chiral) Organocatalyst
Organocatalysts are one of the bravest attempts to mimic enzyme catalysis that Mother Nature uses. Chiral...
1,2-addition
1,2-addition is a type of organic chemical reaction that involves the addition of functional groups to the 1st and 2nd...
1,4-Addition (conjugate addition)
The Michael reaction is the conjugate 1,4-addition of a resonance stabilized carbanion (michael donor) to an activated...
Aldol Reaction
The aldol reaction unites two carbonyl compounds to form a β-hydroxy-carbonyl product, where one carbonyl compound...