Hydroxylation of 3-halooxindoles, 3-bromo-3-(3-chlorobenzyl)indolin-2-one, (E)-benzaldehyde oxime, (S,E)-benzaldehyde O-(3-(3-chlorobenzyl)-2-oxoindolin-3-yl) oxime, 4-((S)-(naphthalen-1-ylmethoxy)((1S,2R,4S,5R)-5-vinylquinuclidin-2-yl)methyl)quinolin-6-ol, Cupreidine Derivative

Organocatalytic Enantioselective Stereoablative Hydroxylation of 3-Halooxindoles: An Effective Method for the Construction of Enantioenriched 3-Substituted 3-Hydroxy-2-Oxindoles.

Reaction Category:

Further reactions | Hydroxylation | Hydroxylation of 3-Halooxindols

Educt:

3-bromo-3-(3-chlorobenzyl)indolin-2-one, (E)-benzaldehyde oxime

Product:

(S,E)-benzaldehyde O-(3-(3-chlorobenzyl)-2-oxoindolin-3-yl) oxime

Catalyst:

4-((S)-(naphthalen-1-ylmethoxy)((1S,2R,4S,5R)-5-vinylquinuclidin-2-yl)methyl)quinolin-6-ol

Cas No:

1101869-04-8

DOI Number:

10.1002/chem.201201395

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Associated Product from Buchler GmbH:

Cupreidine Base

Cas No:

70877-75-7